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Generation of Masked Ti(II) Intermediates from Ti(IV) Amides via β-H Abstraction or Alkyne Deprotonation: An Example of Ti-Catalyzed Nitrene-Coupled Transfer Hydrogenation
Simple Ti amide complexes are shown to act as sources for masked Ti(II) intermediates via several pathways, as demonstrated through the investigation of a unique Ti-catalyzed nitrene-coupled transfer hydrogenation of 3-hexyne. This reaction proceeds through reduction of azobenzene by a masked Ti(II)...
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| Publicado no: | Organometallics |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8315702/ https://ncbi.nlm.nih.gov/pubmed/34321708 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.0c00577 |
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