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Ligand-Controlled Regiodivergence in the Copper-Catalyzed [2,3]- and [1,2]-Rearrangements of Iodonium Ylides

Despite the importance of allylic ylide rearrangements for the synthesis of complex molecules, the catalyst control of [2,3]- and [1,2]-rearrangements remains an unsolved problem. We developed the first regiodivergent [2,3]- and [1,2]-rearrangements of iodonium ylides that are controlled by copper c...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Xu, Bin, Tambar, Uttam K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5937265/
https://ncbi.nlm.nih.gov/pubmed/27603216
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b08624
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