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Enantioselective Synthesis of Pyrrolopyrimidine Scaffolds through Cation-Directed Nucleophilic Aromatic Substitution

The catalytic enantioselective synthesis of 3-aryl-substituted pyrrolopyrimidines (PPYs), a common motif in drug discovery, is achieved through a kinetic resolution via quaternary ammonium salt-catalyzed nucleophilic aromatic substitution (S(N)Ar). Both enantioenriched products and starting material...

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Detalhes bibliográficos
Publicado no:Org Lett
Main Authors: Cardenas, Mariel M., Toenjes, Sean T., Nalbandian, Christopher J., Gustafson, Jeffrey L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5909700/
https://ncbi.nlm.nih.gov/pubmed/29561161
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b00579
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