Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization

Computed descriptors for acyclic diaminocarbene ligands are developed in the context of a gold catalyzed enantioselective tandem [3,3]-sigmatropic rearrangement-[2+2]-cyclization. Surrogate structures enable the rapid identification of parameters that reveal mechanistic characteristics. The observed...

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Bibliographic Details
Published in:J Am Chem Soc
Main Authors: Niemeyer, Zachary L., Pindi, Suresh, Khrakovsky, Dimitri A., Kuzniewski, Christian N., Hong, Cynthia M., Joyce, Leo A., Sigman, Matthew S., Toste, F. Dean
Format: Artigo
Language:Inglês
Published: 2017
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5903265/
https://ncbi.nlm.nih.gov/pubmed/28885017
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b08791
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