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Enantioselective Desymmetrization of Methylenedianilines via Enzyme-Catalyzed Remote Halogenation
Extensive effort has been devoted to engineering flavin-dependent halogenases (FDHs) with improved stability, expanded substrate scope, and altered regioselectivity. Here we show that variants of rebeccamycin halogenase (RebH) catalyze enantioselective desymmetrization of methylenedianilines via hal...
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| 出版年: | J Am Chem Soc |
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| 主要な著者: | , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2018
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5898188/ https://ncbi.nlm.nih.gov/pubmed/29294291 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b09573 |
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