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Reactivity of highly Lewis acidic diborane(4) towards pyridine and isocyanide: formation of boraalkene–pyridine complex and ortho-functionalized pyridine derivatives
The reaction of pinB-BMes(2) (pin = pinacolato, Mes = 2,4,6-Me(3)C(6)H(2)) with Xyl-NC (Xyl = 2,6-Me(2)C(6)H(3)) and pyridine results in the formation of a pyridine-coordinated boraalkene that exhibits an intense color caused by an intramolecular charge-transfer interaction. In the presence of an ex...
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| Publicado en: | Chem Sci |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5887101/ https://ncbi.nlm.nih.gov/pubmed/29675176 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04759b |
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