Carregant...

Reactivity of highly Lewis acidic diborane(4) towards pyridine and isocyanide: formation of boraalkene–pyridine complex and ortho-functionalized pyridine derivatives

The reaction of pinB-BMes(2) (pin = pinacolato, Mes = 2,4,6-Me(3)C(6)H(2)) with Xyl-NC (Xyl = 2,6-Me(2)C(6)H(3)) and pyridine results in the formation of a pyridine-coordinated boraalkene that exhibits an intense color caused by an intramolecular charge-transfer interaction. In the presence of an ex...

Descripció completa

Guardat en:
Dades bibliogràfiques
Publicat a:Chem Sci
Autors principals: Katsuma, Yuhei, Asakawa, Hiroki, Yamashita, Makoto
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2017
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5887101/
https://ncbi.nlm.nih.gov/pubmed/29675176
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc04759b
Etiquetes: Afegir etiqueta
Sense etiquetes, Sigues el primer a etiquetar aquest registre!