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Facile scission of isonitrile carbon–nitrogen triple bond using a diborane(4) reagent
Transition metal reagents and catalysts are generally effective to cleave all three bonds (one σ and two π) in a triple bond despite its high bonding energy. Recently, chemistry of single-bond cleavage by using main-group element compounds is rapidly being developed in the absence of transition meta...
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| Hauptverfasser: | , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
Nature Pub. Group
2014
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4083417/ https://ncbi.nlm.nih.gov/pubmed/24967910 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms5245 |
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