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Structural basis of the Cope rearrangement and cyclization in hapalindole biogenesis

Hapalindole alkaloids are a structurally diverse class of cyanobacterial natural products defined by their varied polycyclic ring systems and diverse biological activities. These complex metabolites are generated from a common biosynthetic intermediate by the Stig cyclases in three mechanistic steps...

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Detalhes bibliográficos
Publicado no:Nat Chem Biol
Main Authors: Newmister, Sean A., Li, Shasha, Garcia-Borràs, Marc, Sanders, Jacob N., Yang, Song, Lowell, Andrew N., Yu, Fengan, Smith, Janet L., Williams, Robert M., Houk, K. N., Sherman, David H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5880276/
https://ncbi.nlm.nih.gov/pubmed/29531360
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41589-018-0003-x
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