Sterically Stabilized Terminal Hydride of a Diiron Dithiolate

The kinetically robust hydride [t-HFe(2)(Me(2)pdt)(CO)(2)(dppv)(2)](+) ([t-H1](+)) (Me(2)pdt(2−) = Me(2)C-(CH(2)S(−))(2); dppv = cis-1,2-C(2)H(2)(PPh(2))(2)) and related derivatives were prepared with (57)Fe enrichment for characterization by NMR, FT-IR, and NRVS. The experimental results were ratio...

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Pubblicato in:Inorg Chem
Autori principali: Carlson, Michaela R., Gray, Danielle L., Richers, Casseday P., Wang, Wenguang, Zhao, Pei-Hua, Rauchfuss, Thomas B., Pelmenschikov, Vladimir, Pham, Cindy C., Gee, Leland B., Wang, Hongxin, Cramer, Stephen P.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2018
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5821139/
https://ncbi.nlm.nih.gov/pubmed/29384371
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.7b02903
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