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Sterically Stabilized Terminal Hydride of a Diiron Dithiolate
The kinetically robust hydride [t-HFe(2)(Me(2)pdt)(CO)(2)(dppv)(2)](+) ([t-H1](+)) (Me(2)pdt(2−) = Me(2)C-(CH(2)S(−))(2); dppv = cis-1,2-C(2)H(2)(PPh(2))(2)) and related derivatives were prepared with (57)Fe enrichment for characterization by NMR, FT-IR, and NRVS. The experimental results were ratio...
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| Veröffentlicht in: | Inorg Chem |
|---|---|
| Hauptverfasser: | , , , , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5821139/ https://ncbi.nlm.nih.gov/pubmed/29384371 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.7b02903 |
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