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Cobalt-Catalyzed Stereoretentive Hydrogen Isotope Exchange of C(sp(3))−H Bonds

Cobalt dialkyl complexes bearing α-diimine ligands proved to be active precatalysts for the nondirected, C(sp(3))−H selective hydrogen isotope exchange (HIE) of alkylarenes using D(2) gas as the deuterium source. Alkylarenes with a variety of substitution patterns and heteroatom substituents on the...

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Xehetasun bibliografikoak
Argitaratua izan da:ACS Catal
Egile Nagusiak: Palmer, W. Neil, Chirik, Paul J.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2017
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC5813831/
https://ncbi.nlm.nih.gov/pubmed/29456876
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b02051
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