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Cobalt-Catalyzed Stereoretentive Hydrogen Isotope Exchange of C(sp(3))−H Bonds
Cobalt dialkyl complexes bearing α-diimine ligands proved to be active precatalysts for the nondirected, C(sp(3))−H selective hydrogen isotope exchange (HIE) of alkylarenes using D(2) gas as the deuterium source. Alkylarenes with a variety of substitution patterns and heteroatom substituents on the...
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| Publicado en: | ACS Catal |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2017
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5813831/ https://ncbi.nlm.nih.gov/pubmed/29456876 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.7b02051 |
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