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Reactivity of hydropersulfides toward hydroxyl radical unraveled: disulfide bond cleavage, hydrogen atom transfer, and proton-coupled electron transfer
Hydropersulfides (RSSH) are highly reactive as nucleophiles and hydrogen atom transfer reagents. These chemical properties are believed to be key for them to act as antioxidants in cells. The reaction involving radical species and the disulfide bond (S-S) in RSSH, a known redox-active group, however...
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| Publicado no: | Phys Chem Chem Phys |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5812807/ https://ncbi.nlm.nih.gov/pubmed/29383342 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cp07570g |
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