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Reactivity of hydropersulfides toward hydroxyl radical unraveled: disulfide bond cleavage, hydrogen atom transfer, and proton-coupled electron transfer

Hydropersulfides (RSSH) are highly reactive as nucleophiles and hydrogen atom transfer reagents. These chemical properties are believed to be key for them to act as antioxidants in cells. The reaction involving radical species and the disulfide bond (S-S) in RSSH, a known redox-active group, however...

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Detaylı Bibliyografya
Yayımlandı:Phys Chem Chem Phys
Asıl Yazarlar: Anglada, Josep M., Crehuet, Ramon, Adhikari, Sarju, Francisco, Joseph S., Xia, Yu
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2018
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC5812807/
https://ncbi.nlm.nih.gov/pubmed/29383342
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cp07570g
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