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Reactivity of hydropersulfides toward hydroxyl radical unraveled: disulfide bond cleavage, hydrogen atom transfer, and proton-coupled electron transfer

Hydropersulfides (RSSH) are highly reactive as nucleophiles and hydrogen atom transfer reagents. These chemical properties are believed to be key for them to act as antioxidants in cells. The reaction involving radical species and the disulfide bond (S-S) in RSSH, a known redox-active group, however...

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Bibliografiske detaljer
Udgivet i:Phys Chem Chem Phys
Main Authors: Anglada, Josep M., Crehuet, Ramon, Adhikari, Sarju, Francisco, Joseph S., Xia, Yu
Format: Artigo
Sprog:Inglês
Udgivet: 2018
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5812807/
https://ncbi.nlm.nih.gov/pubmed/29383342
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cp07570g
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