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A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate 3 Complex—The Product of the Reaction of Nitrogen Monoxide (·NO((g))) with a Ferric-Superoxide Species

Peroxynitrite ((−)OON═O, PN) is a reactive nitrogen species (RNS) which can effect deleterious nitrative or oxidative (bio)chemistry. It may derive from reaction of superoxide anion (O(2)(•−)) with nitric oxide (·NO) and has been suggested to form an as-yet unobserved bound heme-iron-PN intermediate...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Sharma, Savita K., Schaefer, Andrew W., Lim, Hyeongtaek, Matsumura, Hirotoshi, Moënne-Loccoz, Pierre, Hedman, Britt, Hodgson, Keith O., Solomon, Edward I., Karlin, Kenneth D.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5783694/
https://ncbi.nlm.nih.gov/pubmed/29091732
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b08468
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