Oxoiron(IV) Complexes as Synthons for the Assembly of Heterobimetallic Centers such as the Fe/Mn Active Site of Class Ic Ribonucleotide Reductases

Nonheme oxoiron(IV) complexes can serve as synthons for generating heterobimetallic oxo-bridged dimetal complexes by reaction with divalent metal complexes. The formation of Fe(III)–O–Cr(III) and Fe(III)–O–Mn(III) complexes is described herein. The latter complexes may serve as models for the Fe(III...

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Veröffentlicht in:J Biol Inorg Chem
Hauptverfasser: Zhou, Ang, Crossland, Patrick M., Draksharapu, Apparao, Jasniewski, Andrew J., Kleespies, Scott T., Que, Lawrence
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2017
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Article
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5756673/
https://ncbi.nlm.nih.gov/pubmed/29218640
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-017-1517-5
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