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Asymmetric Petasis Borono-Mannich Allylation Reactions Catalyzed by Chiral Biphenols
Chiral biphenols catalyze the asymmetric Petasis borono–Mannich allylation of aldehydes and amines through the use of a bench-stable allyldioxaborolane. The reaction proceeds via a two-step, one-pot process and requires 2 – 8 mol% of 3,3’-Ph(2)-BINOL as the optimal catalyst. Under microwave heating...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5716625/ https://ncbi.nlm.nih.gov/pubmed/28052567 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201611332 |
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