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Asymmetric Propargylation of Ketones using Allenylboronates Catalyzed by Chiral Biphenols
[Image: see text] Chiral biphenols catalyze the enantioselective asymmetric propargylation of ketones using allenylboronates. The reaction uses 10 mol % of 3,3′-Br(2)-BINOL as the catalyst and allenyldioxoborolane as the nucleophile, in the absence of solvent, and under microwave irradiation to affo...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2011
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3155969/ https://ncbi.nlm.nih.gov/pubmed/21732609 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol201535b |
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