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Mechanism and an Improved Asymmetric Allylboration of Ketones Catalyzed by Chiral Biphenols
A mechanistic study of the enantioselective asymmetric allylboration of ketones with allyldiisopropoxyborane catalyzed by chiral biphenols resulted in the development of improved reaction process. In a ligand exchange process involving the chiral biphenol and the boronate to liberate isopropanol as...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2819187/ https://ncbi.nlm.nih.gov/pubmed/19816902 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200904715 |
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