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Asymmetric Allylboration of Acyl Imines Catalyzed by Chiral Diols
Chiral BINOL-derived diols catalyze the enantioselective asymmetric allylboration of acyl imines. The reaction requires 15 mol% of (S)-3,3′-Ph(2)-BINOL as the catalyst and allyldiisopropoxyborane as the nucleophile. The reaction products are obtained in good yields (75 – 94%) and high enantiomeric r...
Tallennettuna:
| Päätekijät: | , , |
|---|---|
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
2007
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2638762/ https://ncbi.nlm.nih.gov/pubmed/18020334 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja075204v |
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