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Asymmetric Allylboration of Acyl Imines Catalyzed by Chiral Diols

Chiral BINOL-derived diols catalyze the enantioselective asymmetric allylboration of acyl imines. The reaction requires 15 mol% of (S)-3,3′-Ph(2)-BINOL as the catalyst and allyldiisopropoxyborane as the nucleophile. The reaction products are obtained in good yields (75 – 94%) and high enantiomeric r...

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Main Authors: Lou, Sha, Moquist, Philip N., Schaus, Scott E.
格式: Artigo
語言:Inglês
出版: 2007
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2638762/
https://ncbi.nlm.nih.gov/pubmed/18020334
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja075204v
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