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Enantioselective Additions of Boronates to Chromene Acetals Catalyzed by a Chiral Brønsted acid-Lewis acid System

[Image: see text] Chiral α,β-dihydroxy carboxylic acids catalyze the enantioselective addition of alkenyl- and aryl boronates to chromene acetals. The optimal carboxylic acid is a tartaric acid amide, easily synthesized via a 3-step procedure. The reaction is enhanced by the addition of Lanthanide t...

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Bibliographic Details
Main Authors: Moquist, Philip N., Kodama, Tomohiro, Schaus, Scott E.
Format: Artigo
Language:Inglês
Published: 2010
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3035997/
https://ncbi.nlm.nih.gov/pubmed/20721997
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201003469
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