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Asymmetric Traceless Petasis Borono-Mannich Reactions of Enals: Reductive Transpositions of Allylic Diazenes

The traceless Petasis borono-Mannich reaction of enals, sulfonylhydrazines, and allylboronates catalyzed by chiral biphenols results in an asymmetric reductive transposition of the in situ generated allylic diazene. Acyclic 1,4-diene products bearing alkyl- or aryl- substituted benzylic stereocenter...

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Foilsithe in:Angew Chem Int Ed Engl
Main Authors: Jiang, Yao, Thomson, Regan J., Schaus, Scott E.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2017
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5739942/
https://ncbi.nlm.nih.gov/pubmed/29110383
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201708784
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