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Asymmetric Traceless Petasis Borono-Mannich Reactions of Enals: Reductive Transpositions of Allylic Diazenes
The traceless Petasis borono-Mannich reaction of enals, sulfonylhydrazines, and allylboronates catalyzed by chiral biphenols results in an asymmetric reductive transposition of the in situ generated allylic diazene. Acyclic 1,4-diene products bearing alkyl- or aryl- substituted benzylic stereocenter...
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5739942/ https://ncbi.nlm.nih.gov/pubmed/29110383 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201708784 |
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