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α-Silyl Amides: Effective Bifunctional Lynchpins for Type I Anion Relay Chemistry
Lynchpins comprising α-silyl amides have been validated for type I anion relay chemistry (ARC) to permit ready access to γ-ketoamides. Importantly, the ARC protocol can be run at ambient temperature without the need of additional reagents to trigger the [1,4] Brook rearrangement.
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| Udgivet i: | Org Lett |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2017
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5712993/ https://ncbi.nlm.nih.gov/pubmed/29120188 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.7b03142 |
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