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Benzyl and Phenylthiomethyl Silanes: A New Class of Bifunctional Linchpins for Type II Anion Relay Chemistry (ARC)

[Image: see text] A new class of bifunctional linchpins bearing electrophilic sites β or γ to a silyl group have been designed, synthesized and demonstrated to be competent in tri-component unions exploiting Type II Anion Relay Chemistry (ARC). High diastereoselectivities were observed when a phenyl...

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Detalhes bibliográficos
Main Authors: Smith, Amos B., Tong, Rongbiao
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2844645/
https://ncbi.nlm.nih.gov/pubmed/20180531
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100130x
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