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Comparisons of lanthanide/actinide +2 ions in a tris(aryloxide)arene coordination environment
A new series of Ln(3+) and Ln(2+) complexes has been synthesized using the tris(aryloxide)arene ligand system, (((Ad,Me)ArO)(3)mes)(3–), recently used to isolate a complex of U(2+). The triphenol precursor, ((Ad,Me)ArOH)(3)mes, reacts with the Ln(3+) amides, Ln(NR(2))(3) (R = SiMe(3)), to form a ser...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5674182/ https://ncbi.nlm.nih.gov/pubmed/29163894 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02337e |
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