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Synthesis, structure, and reactivity of crystalline molecular complexes of the {[C(5)H(3)(SiMe(3))(2)](3)Th}(1–) anion containing thorium in the formal +2 oxidation state
Reduction of the Th(3+) complex Cp′′3Th, 1 [Cp′′ = C(5)H(3)(SiMe(3))(2)], with potassium graphite in THF in the presence of 2.2.2-cryptand generates [K(2.2.2-cryptand)][Cp′′3Th], 2, a complex containing thorium in the formal +2 oxidation state. Reaction of 1 with KC(8) in the presence of 18-crown-6...
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| 發表在: | Chem Sci |
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| Main Authors: | , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
Royal Society of Chemistry
2015
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5811171/ https://ncbi.nlm.nih.gov/pubmed/29560172 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03033h |
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