Evaluating the electronic structure of formal Ln(II) ions in Ln(II)(C(5)H(4)SiMe(3))(3) (1–) using XANES spectroscopy and DFT calculations

The isolation of [K(2.2.2-cryptand)][Ln(C(5)H(4)SiMe(3))(3)], formally containing Ln(II), for all lanthanides (excluding Pm) was surprising given that +2 oxidation states are typically regarded as inaccessible for most 4f-elements. Herein, X-ray absorption near-edge spectroscopy (XANES), ground-stat...

Description complète

Enregistré dans:
Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Fieser, Megan E., Ferrier, Maryline G., Su, Jing, Batista, Enrique, Cary, Samantha K., Engle, Jonathan W., Evans, William J., Lezama Pacheco, Juan S., Kozimor, Stosh A., Olson, Angela C., Ryan, Austin J., Stein, Benjamin W., Wagner, Gregory L., Woen, David H., Vitova, Tonya, Yang, Ping
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2017
Sujets:
Chemistry
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5625586/
https://ncbi.nlm.nih.gov/pubmed/28989638
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00825b
Tags: Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!

Documents similaires