Evaluating the electronic structure of formal Ln(II) ions in Ln(II)(C(5)H(4)SiMe(3))(3) (1–) using XANES spectroscopy and DFT calculations

The isolation of [K(2.2.2-cryptand)][Ln(C(5)H(4)SiMe(3))(3)], formally containing Ln(II), for all lanthanides (excluding Pm) was surprising given that +2 oxidation states are typically regarded as inaccessible for most 4f-elements. Herein, X-ray absorption near-edge spectroscopy (XANES), ground-stat...

Cur síos iomlán

Na minha lista:
Sonraí Bibleagrafaíochta
Foilsithe in:Chem Sci
Main Authors: Fieser, Megan E., Ferrier, Maryline G., Su, Jing, Batista, Enrique, Cary, Samantha K., Engle, Jonathan W., Evans, William J., Lezama Pacheco, Juan S., Kozimor, Stosh A., Olson, Angela C., Ryan, Austin J., Stein, Benjamin W., Wagner, Gregory L., Woen, David H., Vitova, Tonya, Yang, Ping
Formáid: Artigo
Teanga:Inglês
Foilsithe: Royal Society of Chemistry 2017
Ábhair:
Chemistry
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5625586/
https://ncbi.nlm.nih.gov/pubmed/28989638
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00825b
Clibeanna: Cuir Clib Leis
Gan Chlibeanna, Bí ar an gcéad duine leis an taifead seo a chlibeáil!

Míreanna Comhchosúla