Evaluating the electronic structure of formal Ln(II) ions in Ln(II)(C(5)H(4)SiMe(3))(3) (1–) using XANES spectroscopy and DFT calculations

The isolation of [K(2.2.2-cryptand)][Ln(C(5)H(4)SiMe(3))(3)], formally containing Ln(II), for all lanthanides (excluding Pm) was surprising given that +2 oxidation states are typically regarded as inaccessible for most 4f-elements. Herein, X-ray absorption near-edge spectroscopy (XANES), ground-stat...

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Gorde:
Xehetasun bibliografikoak
Argitaratua izan da:Chem Sci
Egile Nagusiak: Fieser, Megan E., Ferrier, Maryline G., Su, Jing, Batista, Enrique, Cary, Samantha K., Engle, Jonathan W., Evans, William J., Lezama Pacheco, Juan S., Kozimor, Stosh A., Olson, Angela C., Ryan, Austin J., Stein, Benjamin W., Wagner, Gregory L., Woen, David H., Vitova, Tonya, Yang, Ping
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: Royal Society of Chemistry 2017
Gaiak:
Chemistry
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC5625586/
https://ncbi.nlm.nih.gov/pubmed/28989638
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00825b
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