Comparisons of lanthanide/actinide +2 ions in a tris(aryloxide)arene coordination environment

A new series of Ln(3+) and Ln(2+) complexes has been synthesized using the tris(aryloxide)arene ligand system, (((Ad,Me)ArO)(3)mes)(3–), recently used to isolate a complex of U(2+). The triphenol precursor, ((Ad,Me)ArOH)(3)mes, reacts with the Ln(3+) amides, Ln(NR(2))(3) (R = SiMe(3)), to form a ser...

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Publicado en:Chem Sci
Autores principales: Fieser, Megan E., Palumbo, Chad T., La Pierre, Henry S., Halter, Dominik P., Voora, Vamsee K., Ziller, Joseph W., Furche, Filipp, Meyer, Karsten, Evans, William J.
Formato: Artigo
Lenguaje:Inglês
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5674182/
https://ncbi.nlm.nih.gov/pubmed/29163894
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02337e
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