Cargando...
Rhodium-Catalyzed Enantioselective Radical Addition of CX(4) Reagents to Olefins
We describe an enantioselective addition of Br-CX(3) (X = Cl or Br) to terminal olefins that introduces a trihalomethyl group and generates optically active secondary bromides. Computational and experimental evidence supports an asymmetric atom transfer radical addition (ATRA) mechanism in which the...
Guardado en:
| Publicado en: | Angew Chem Int Ed Engl |
|---|---|
| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2017
|
| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5672916/ https://ncbi.nlm.nih.gov/pubmed/28544237 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201704074 |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|