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Rhodium-Catalyzed Enantioselective Radical Addition of CX(4) Reagents to Olefins
We describe an enantioselective addition of Br-CX(3) (X = Cl or Br) to terminal olefins that introduces a trihalomethyl group and generates optically active secondary bromides. Computational and experimental evidence supports an asymmetric atom transfer radical addition (ATRA) mechanism in which the...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5672916/ https://ncbi.nlm.nih.gov/pubmed/28544237 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201704074 |
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