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Intramolecular C–H and C–F Bond Oxygenation by Site-Differentiated Tetranuclear Manganese Models of the OEC
The dangler manganese center in the oxygen-evolving complex (OEC) of photosystem II plays an important role in the oxidation of water to dioxygen. Inspired by the structure of the OEC, we synthesized a series of site-differentiated tetra-manganese clusters [LMn(3)(PhPz)(3)OMn] [OTf]x (2: x = 2; 3: x...
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| Pubblicato in: | Inorg Chem |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2017
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5669799/ https://ncbi.nlm.nih.gov/pubmed/28731687 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.7b01022 |
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