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Intramolecular C–H and C–F Bond Oxygenation by Site-Differentiated Tetranuclear Manganese Models of the OEC

The dangler manganese center in the oxygen-evolving complex (OEC) of photosystem II plays an important role in the oxidation of water to dioxygen. Inspired by the structure of the OEC, we synthesized a series of site-differentiated tetra-manganese clusters [LMn(3)(PhPz)(3)OMn] [OTf]x (2: x = 2; 3: x...

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Xehetasun bibliografikoak
Argitaratua izan da:Inorg Chem
Egile Nagusiak: Carsch, Kurtis M., de Ruiter, Graham, Agapie, Theodor
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2017
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC5669799/
https://ncbi.nlm.nih.gov/pubmed/28731687
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.7b01022
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