Accelerated Oxygen Atom Transfer and C–H Bond Oxygenation by Remote Redox Changes in Fe(3)Mn-Iodosobenzene Adducts

We report the synthesis, characterization, and reactivity of [LFe(3)(PhPz)(3)OMn((s)PhIO)][OTf](x) (3: x = 2; 4: x = 3), where 4 is one of very few examples of iodosobenzene–metal adducts characterized by X-ray crystallography. Access to these rare heterometallic clusters enabled differentiation of...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: de Ruiter, Graham, Carsch, Kurtis M., Gul, Sheraz, Chatterjee, Ruchira, Thompson, Niklas B., Takase, Michael K., Yano, Junko, Agapie, Theodor
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5505263/
https://ncbi.nlm.nih.gov/pubmed/28338266
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201701319
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