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Accelerated Oxygen Atom Transfer and C–H Bond Oxygenation by Remote Redox Changes in Fe(3)Mn-Iodosobenzene Adducts
We report the synthesis, characterization, and reactivity of [LFe(3)(PhPz)(3)OMn((s)PhIO)][OTf](x) (3: x = 2; 4: x = 3), where 4 is one of very few examples of iodosobenzene–metal adducts characterized by X-ray crystallography. Access to these rare heterometallic clusters enabled differentiation of...
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| Veröffentlicht in: | Angew Chem Int Ed Engl |
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| Hauptverfasser: | , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2017
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5505263/ https://ncbi.nlm.nih.gov/pubmed/28338266 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201701319 |
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