Wordt geladen...
Selectivity of C–H vs. C–F Bond Oxygenation by Homo- and Heterometallic Fe(4), Fe(3)Mn, and Mn(4) Clusters
A series of tetranuclear [LM(3)(HFArPz)(3)OM′][OTf](2) (M, M′ = Fe or Mn) clusters that displays 3-(2-fluorophenyl)pyrazolate (HFArPz) as bridging ligand is reported. With these complexes manganese is demonstrated to facilitate C(sp(2)) –F bond oxygenation via a putative terminal metal-oxo species....
Bewaard in:
| Gepubliceerd in: | Chemistry |
|---|---|
| Hoofdauteurs: | , , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
2017
|
| Onderwerpen: | |
| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5659184/ https://ncbi.nlm.nih.gov/pubmed/28658508 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201702302 |
| Tags: |
Voeg label toe
Geen labels, Wees de eerste die dit record labelt!
|