Selectivity of C–H vs. C–F Bond Oxygenation by Homo- and Heterometallic Fe(4), Fe(3)Mn, and Mn(4) Clusters

A series of tetranuclear [LM(3)(HFArPz)(3)OM′][OTf](2) (M, M′ = Fe or Mn) clusters that displays 3-(2-fluorophenyl)pyrazolate (HFArPz) as bridging ligand is reported. With these complexes manganese is demonstrated to facilitate C(sp(2)) –F bond oxygenation via a putative terminal metal-oxo species....

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Bibliographic Details
Published in:Chemistry
Main Authors: de Ruiter, Graham, Carsch, Kurtis M., Takase, Michael K., Agapie, Theodor
Format: Artigo
Language:Inglês
Published: 2017
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5659184/
https://ncbi.nlm.nih.gov/pubmed/28658508
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201702302
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