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Metalloradical Reactivity of Ru(I) and Ru(0) Stabilized by an Indole‐Based Tripodal Tetraphosphine Ligand
The tripodal, tetradentate tris(1‐(diphenylphosphanyl)‐3‐methyl‐1H‐indol‐2‐yl)phosphane PP(3)‐ligand 1 stabilizes Ru in the Ru(II), Ru(I), and Ru(0) oxidation states. The octahedral [(PP(3))Ru(II)(Cl)(2)] (2), distorted trigonal bipyramidal [(PP(3))Ru(I)(Cl)] (3), and trigonal bipyramidal [(PP(3))Ru...
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| Publicado en: | Chemistry |
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| Autores principales: | , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
John Wiley and Sons Inc.
2017
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5639366/ https://ncbi.nlm.nih.gov/pubmed/28857278 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201702727 |
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