Dehydrogenation of formic acid by Ir–bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand

The synthesis and tautomeric nature of three xanthene-based bisMETAMORPhos ligands (La–Lc) is reported. Coordination of these bis(sulfonamidophosphines) to Ir(acac)(cod) initially leads to the formation of Ir(I)(L (H)) species (1a), which convert via formal oxidative addition of the ligand to Ir(III...

Disgrifiad llawn

Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Chem Sci
Prif Awduron: Oldenhof, Sander, Lutz, Martin, de Bruin, Bas, Ivar van der Vlugt, Jarl, Reek, Joost N. H.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: Royal Society of Chemistry 2015
Pynciau:
Chemistry
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC5811074/
https://ncbi.nlm.nih.gov/pubmed/29560190
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc02555e
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