Metalloradical Reactivity of Ru(I) and Ru(0) Stabilized by an Indole‐Based Tripodal Tetraphosphine Ligand

The tripodal, tetradentate tris(1‐(diphenylphosphanyl)‐3‐methyl‐1H‐indol‐2‐yl)phosphane PP(3)‐ligand 1 stabilizes Ru in the Ru(II), Ru(I), and Ru(0) oxidation states. The octahedral [(PP(3))Ru(II)(Cl)(2)] (2), distorted trigonal bipyramidal [(PP(3))Ru(I)(Cl)] (3), and trigonal bipyramidal [(PP(3))Ru...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: van de Watering, Fenna F., van der Vlugt, Jarl Ivar, Dzik, Wojciech I., de Bruin, Bas, Reek, Joost N. H.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5639366/
https://ncbi.nlm.nih.gov/pubmed/28857278
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201702727
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