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Catalytic Synthesis of 8‐Membered Ring Compounds via Cobalt(III)‐Carbene Radicals
The metalloradical activation of o‐aryl aldehydes with tosylhydrazide and a cobalt(II) porphyrin catalyst produces cobalt(III)‐carbene radical intermediates, providing a new and powerful strategy for the synthesis of medium‐sized ring structures. Herein we make use of the intrinsic radical‐type reac...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7317878/ https://ncbi.nlm.nih.gov/pubmed/32259369 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202002674 |
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