Catalytic Synthesis of 8‐Membered Ring Compounds via Cobalt(III)‐Carbene Radicals

The metalloradical activation of o‐aryl aldehydes with tosylhydrazide and a cobalt(II) porphyrin catalyst produces cobalt(III)‐carbene radical intermediates, providing a new and powerful strategy for the synthesis of medium‐sized ring structures. Herein we make use of the intrinsic radical‐type reac...

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Udgivet i:Angew Chem Int Ed Engl
Main Authors: Zhou, Minghui, Lankelma, Marianne, van der Vlugt, Jarl Ivar, de Bruin, Bas
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2020
Fag:
Research Articles
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7317878/
https://ncbi.nlm.nih.gov/pubmed/32259369
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202002674
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