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Synthetic control and empirical prediction of redox potentials for Co(4)O(4) cubanes over a 1.4 V range: implications for catalyst design and evaluation of high-valent intermediates in water oxidation

The oxo-cobalt cubane unit [Co(4)O(4)] is of interest as a homogeneous oxygen-evolution reaction (OER) catalyst, and as a functional mimic of heterogeneous cobalt oxide OER catalysts. The synthesis of several new cubanes allows evaluation of redox potentials for the [Co(4)O(4)] cluster, which are hi...

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Bibliografiska uppgifter
I publikationen:Chem Sci
Huvudupphovsmän: Nguyen, Andy I., Wang, Jianing, Levine, Daniel S., Ziegler, Micah S., Tilley, T. Don
Materialtyp: Artigo
Språk:Inglês
Publicerad: Royal Society of Chemistry 2017
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5635813/
https://ncbi.nlm.nih.gov/pubmed/29081963
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00627f
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