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Synthetic control and empirical prediction of redox potentials for Co(4)O(4) cubanes over a 1.4 V range: implications for catalyst design and evaluation of high-valent intermediates in water oxidation
The oxo-cobalt cubane unit [Co(4)O(4)] is of interest as a homogeneous oxygen-evolution reaction (OER) catalyst, and as a functional mimic of heterogeneous cobalt oxide OER catalysts. The synthesis of several new cubanes allows evaluation of redox potentials for the [Co(4)O(4)] cluster, which are hi...
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| Yayımlandı: | Chem Sci |
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| Asıl Yazarlar: | , , , , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
Royal Society of Chemistry
2017
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5635813/ https://ncbi.nlm.nih.gov/pubmed/29081963 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00627f |
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