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Enhancing the reactivity of nickel(ii) in hydrogen evolution reactions (HERs) by β-hydrogenation of porphyrinoid ligands
Fine-tuning of the porphyrin β-periphery is important for naturally occurring metal tetrapyrroles to exert diverse biological roles. Here we describe how this approach is also applied to design molecular catalysts, as exemplified by Ni(ii) porphyrinoids catalyzing the hydrogen evolution reaction (HE...
Tallennettuna:
| Julkaisussa: | Chem Sci |
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| Päätekijät: | , , , , , , , |
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
Royal Society of Chemistry
2017
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5620542/ https://ncbi.nlm.nih.gov/pubmed/28989625 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02073b |
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