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Cationic nickel porphyrinoids with unexpected reactivity

Cationic nickel(ii) complexes of two ring-contracted porphyrinoid ligands distantly related to the corrins were prepared by metal templated macrocyclisation. The compounds show reversible electron transfer processes and were found to be the first porphyrinoid-based catalysts for C–C cross-coupling....

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Wicht, Richard, Bahnmüller, Stefanie, Brandhorst, Kai, Schweyen, Peter, Bröring, Martin
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5952870/
https://ncbi.nlm.nih.gov/pubmed/29896348
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03663a
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