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Synthesis of Highly Oxygenated Carbocycles by Stereoselective Coupling of Alkynes to 1,3- and 1,4-Dicarbonyl Systems

[Image: see text] Densely substituted and highly oxygenated carbocycles are challenging targets for synthesis. In particular, those possessing numerous contiguous, fully substituted carbon atoms (i.e., tertiary alcohols and quaternary centers) are often not accessible in a direct fashion, necessitat...

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Pubblicato in:J Am Chem Soc
Autori principali: Kier, Matthew J., Leon, Robert M., O’Rourke, Natasha F., Rheingold, Arnold L., Micalizio, Glenn C.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2017
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5600187/
https://ncbi.nlm.nih.gov/pubmed/28844136
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b06286
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