Intermediates in the oxygenation of a nonheme diiron(II) complex, including the first evidence for a bound superoxo species

The reaction of [Fe(2)(μ-OH)(2)(6-Me(3)-TPA)(2)](2+) (1) [6-Me(3)-TPA, Tris(6-methyl-2-pyridylmethyl)amine] with O(2) in CH(2)Cl(2) at –80°C gives rise to two new intermediates, 2 and 3, before the formation of previously characterized [Fe(2)(O)(O(2))(6-Me(3)-TPA)(2)](2+) (4) that allow the oxygenat...

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Detaylı Bibliyografya
Asıl Yazarlar: Shan, Xiaopeng, Que, Lawrence
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: National Academy of Sciences 2005
Konular:
Physical Sciences
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC556236/
https://ncbi.nlm.nih.gov/pubmed/15802473
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0409640102
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