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Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes

A growing subset of metalloenzymes activates dioxygen with nonheme diiron active sites to effect substrate oxidations that range from the hydroxylation of methane and the desaturation of fatty acids to the deformylation of fatty aldehydes to produce alkanes and the six-electron oxidation of aminoare...

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Detalhes bibliográficos
Publicado no:Chem Rev
Main Authors: Jasniewski, Andrew J., Que, Lawrence
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5920527/
https://ncbi.nlm.nih.gov/pubmed/29400961
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.chemrev.7b00457
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