Nuclear resonance vibrational spectroscopic and computational study of high-valent diiron complexes relevant to enzyme intermediates

High-valent intermediates of binuclear nonheme iron enzymes are structurally unknown despite their importance for understanding enzyme reactivity. Nuclear resonance vibrational spectroscopy combined with density functional theory calculations has been applied to structurally well-characterized high-...

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Bibliographic Details
Main Authors: Park, Kiyoung, Bell, Caleb B., Liu, Lei V., Wang, Dong, Xue, Genqiang, Kwak, Yeonju, Wong, Shaun D., Light, Kenneth M., Zhao, Jiyong, Alp, E. Ercan, Yoda, Yoshitaka, Saito, Makina, Kobayashi, Yasuhiro, Ohta, Takehiro, Seto, Makoto, Que, Lawrence, Solomon, Edward I.
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2013
Subjects:
Physical Sciences
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3631696/
https://ncbi.nlm.nih.gov/pubmed/23576760
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1304238110
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