Nuclear resonance vibrational spectroscopic and computational study of high-valent diiron complexes relevant to enzyme intermediates

High-valent intermediates of binuclear nonheme iron enzymes are structurally unknown despite their importance for understanding enzyme reactivity. Nuclear resonance vibrational spectroscopy combined with density functional theory calculations has been applied to structurally well-characterized high-...

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Główni autorzy: Park, Kiyoung, Bell, Caleb B., Liu, Lei V., Wang, Dong, Xue, Genqiang, Kwak, Yeonju, Wong, Shaun D., Light, Kenneth M., Zhao, Jiyong, Alp, E. Ercan, Yoda, Yoshitaka, Saito, Makina, Kobayashi, Yasuhiro, Ohta, Takehiro, Seto, Makoto, Que, Lawrence, Solomon, Edward I.
Format: Artigo
Język:Inglês
Wydane: National Academy of Sciences 2013
Hasła przedmiotowe:
Physical Sciences
Dostęp online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3631696/
https://ncbi.nlm.nih.gov/pubmed/23576760
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1304238110
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