Nuclear resonance vibrational spectroscopic definition of peroxy intermediates in non-heme iron sites

Fe(III)-(hydro)peroxy intermediates have been isolated in two classes of mononuclear non-heme Fe enzymes that are important in bioremediation: the Rieske dioxygenases and the extradiol dioxygenases. The binding mode and protonation state of the peroxide moieties in these intermediates are not well d...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Sutherlin, Kyle D., Liu, Lei V., Lee, Yong-Min, Kwak, Yeonju, Yoda, Yoshitaka, Saito, Makina, Kurokuzu, Masayuki, Kobayashi, Yasuhiro, Seto, Makoto, Que, Lawrence, Nam, Wonwoo, Solomon, Edward I.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5312706/
https://ncbi.nlm.nih.gov/pubmed/27726349
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b07227
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